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An ideal gas is a theoretical gas composed of many randomly moving point particles that do not interact except when they collide elastically. The ideal gas concept is useful because it obeys the ideal gas law, a simplified equation of state, and is amenable to analysis under statistical mechanics. One mole of an ideal gas has a volume of 22.7 L at STP as defined by IUPAC. At normal conditions such as standard temperature and pressure, most real gases behave qualitatively like an ideal gas. Many gases such as nitrogen, oxygen, hydrogen, noble gases, and some heavier gases like carbon dioxide can be treated like ideal gases within reasonable tolerances. Generally, a gas behaves more like an ideal gas at higher temperature and lower pressure,〔 as the potential energy due to intermolecular forces becomes less significant compared with the particles' kinetic energy, and the size of the molecules becomes less significant compared to the empty space between them. The ideal gas model tends to fail at lower temperatures or higher pressures, when intermolecular forces and molecular size become important. It also fails for most heavy gases, such as many refrigerants,〔 and for gases with strong intermolecular forces, notably water vapor. At high pressures, the volume of a real gas is often considerably greater than that of an ideal gas. At low temperatures, the pressure of a real gas is often considerably less than that of an ideal gas. At some point of low temperature and high pressure, real gases undergo a phase transition, such as to a liquid or a solid. The model of an ideal gas, however, does not describe or allow phase transitions. These must be modeled by more complex equations of state. The deviation from the ideal gas behaviour can be described by a dimensionless quantity, the compressibility factor, Z. The ideal gas model has been explored in both the Newtonian dynamics (as in "kinetic theory") and in quantum mechanics (as a "gas in a box"). The ideal gas model has also been used to model the behavior of electrons in a metal (in the Drude model and the free electron model), and it is one of the most important models in statistical mechanics. ==Types of ideal gas== There are three basic classes of ideal gas: * the classical or Maxwell–Boltzmann ideal gas, * the ideal quantum Bose gas, composed of bosons, and * the ideal quantum Fermi gas, composed of fermions. The classical ideal gas can be separated into two types: The classical thermodynamic ideal gas and the ideal quantum Boltzmann gas. Both are essentially the same, except that the classical thermodynamic ideal gas is based on classical statistical mechanics, and certain thermodynamic parameters such as the entropy are only specified to within an undetermined additive constant. The ideal quantum Boltzmann gas overcomes this limitation by taking the limit of the quantum Bose gas and quantum Fermi gas in the limit of high temperature to specify these additive constants. The behavior of a quantum Boltzmann gas is the same as that of a classical ideal gas except for the specification of these constants. The results of the quantum Boltzmann gas are used in a number of cases including the Sackur–Tetrode equation for the entropy of an ideal gas and the Saha ionization equation for a weakly ionized plasma. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「ideal gas」の詳細全文を読む スポンサード リンク
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